Azure App Service is a scalable platform, it can automatically scale out when there’s unexpected load. But it has to be configured properly to know when to scale out.
Configure App Service to scale out to multiple instances if the CPU usage goes beyond 60%. Generate some load using your favourite tool and observe the number of instances going up, and down when the load is terminated.
There’s a multitude of different ways to generate requests, you could use the included JMeter file, or run an ACI container with wrk to generate the load.